Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.
Identifieur interne : 001736 ( Main/Exploration ); précédent : 001735; suivant : 001737Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.
Auteurs : Thrinathreddy Ramireddy [Australie] ; Neeraj Sharma [Australie] ; Tan Xing [Australie] ; Ying Chen [Australie] ; Jeremie Leforestier [Australie] ; Alexey M. Glushenkov [Australie]Source :
- ACS applied materials & interfaces [ 1944-8252 ] ; 2016.
Abstract
Sodium-ion batteries are in the spotlight as viable alternatives to lithium-ion batteries in stationary storage and power grid applications. Among possible anode materials, Sb is one of the interesting candidates due to a combination of battery-type potential plateaus in the charge-discharge profiles, high capacity (theoretical capacity of 660 mAh g(-1)), and demonstrated good cyclic stability. The influence of Sb particle size (particularly at the nanoscale range) and the composition of Sb-carbon composites on the electrode performance, stability, and charge storage mechanism is systematically evaluated here for the first time. A range of Sb-carbon nanocomposites with varied Sb particle size (between 50 and ∼1 nm) are studied. The control of the particle size is achieved via varying the carbon and Sb weight ratio in the precursors. The shape of charge-discharge profiles, hysteresis, and the difference in cyclic stabilities and rate performance are analyzed. The nanocomposite with the smallest particle size (∼1 nm) and the largest carbon content provides the most stable cyclic behavior and a better rate capability but suffers from an increased hysteresis between charge and discharge curves. In situ synchrotron X-ray diffraction experiments indicate that the storage mechanism in the Sb-carbon nanocomposites containing Sb nanoparticles is different from the electrodes with bulkier, micron-sized Sb particles, and the electrochemical reaction proceeds through a number of crystalline intermediates.
DOI: 10.1021/acsami.6b09619
PubMed: 27753471
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream PubMed, to step Corpus: 001665
- to stream PubMed, to step Curation: 001643
- to stream PubMed, to step Checkpoint: 001643
- to stream Ncbi, to step Merge: 003D27
- to stream Ncbi, to step Curation: 003D27
- to stream Ncbi, to step Checkpoint: 003D27
- to stream Main, to step Merge: 001731
- to stream Main, to step Curation: 001736
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.</title><author><name sortKey="Ramireddy, Thrinathreddy" sort="Ramireddy, Thrinathreddy" uniqKey="Ramireddy T" first="Thrinathreddy" last="Ramireddy">Thrinathreddy Ramireddy</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Sharma, Neeraj" sort="Sharma, Neeraj" uniqKey="Sharma N" first="Neeraj" last="Sharma">Neeraj Sharma</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemistry, University of New South Wales , Sydney, New South Wales 2052, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, University of New South Wales , Sydney, New South Wales 2052</wicri:regionArea><wicri:noRegion>New South Wales 2052</wicri:noRegion></affiliation></author><author><name sortKey="Xing, Tan" sort="Xing, Tan" uniqKey="Xing T" first="Tan" last="Xing">Tan Xing</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Chen, Ying" sort="Chen, Ying" uniqKey="Chen Y" first="Ying" last="Chen">Ying Chen</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Leforestier, Jeremie" sort="Leforestier, Jeremie" uniqKey="Leforestier J" first="Jeremie" last="Leforestier">Jeremie Leforestier</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Glushenkov, Alexey M" sort="Glushenkov, Alexey M" uniqKey="Glushenkov A" first="Alexey M" last="Glushenkov">Alexey M. Glushenkov</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2016">2016</date><idno type="RBID">pubmed:27753471</idno><idno type="pmid">27753471</idno><idno type="doi">10.1021/acsami.6b09619</idno><idno type="wicri:Area/PubMed/Corpus">001665</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Corpus" wicri:corpus="PubMed">001665</idno><idno type="wicri:Area/PubMed/Curation">001643</idno><idno type="wicri:explorRef" wicri:stream="PubMed" wicri:step="Curation">001643</idno><idno type="wicri:Area/PubMed/Checkpoint">001643</idno><idno type="wicri:explorRef" wicri:stream="Checkpoint" wicri:step="PubMed">001643</idno><idno type="wicri:Area/Ncbi/Merge">003D27</idno><idno type="wicri:Area/Ncbi/Curation">003D27</idno><idno type="wicri:Area/Ncbi/Checkpoint">003D27</idno><idno type="wicri:Area/Main/Merge">001731</idno><idno type="wicri:Area/Main/Curation">001736</idno><idno type="wicri:Area/Main/Exploration">001736</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.</title><author><name sortKey="Ramireddy, Thrinathreddy" sort="Ramireddy, Thrinathreddy" uniqKey="Ramireddy T" first="Thrinathreddy" last="Ramireddy">Thrinathreddy Ramireddy</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Sharma, Neeraj" sort="Sharma, Neeraj" uniqKey="Sharma N" first="Neeraj" last="Sharma">Neeraj Sharma</name><affiliation wicri:level="1"><nlm:affiliation>School of Chemistry, University of New South Wales , Sydney, New South Wales 2052, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>School of Chemistry, University of New South Wales , Sydney, New South Wales 2052</wicri:regionArea><wicri:noRegion>New South Wales 2052</wicri:noRegion></affiliation></author><author><name sortKey="Xing, Tan" sort="Xing, Tan" uniqKey="Xing T" first="Tan" last="Xing">Tan Xing</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Chen, Ying" sort="Chen, Ying" uniqKey="Chen Y" first="Ying" last="Chen">Ying Chen</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Leforestier, Jeremie" sort="Leforestier, Jeremie" uniqKey="Leforestier J" first="Jeremie" last="Leforestier">Jeremie Leforestier</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author><author><name sortKey="Glushenkov, Alexey M" sort="Glushenkov, Alexey M" uniqKey="Glushenkov A" first="Alexey M" last="Glushenkov">Alexey M. Glushenkov</name><affiliation wicri:level="1"><nlm:affiliation>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216, Australia.</nlm:affiliation><country xml:lang="fr">Australie</country><wicri:regionArea>Institute for Frontier Materials, Deakin University , 75 Pigdons Road, Waurn Ponds, Geelong, Victoria 3216</wicri:regionArea><wicri:noRegion>Victoria 3216</wicri:noRegion></affiliation></author></analytic><series><title level="j">ACS applied materials & interfaces</title><idno type="eISSN">1944-8252</idno><imprint><date when="2016" type="published">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Sodium-ion batteries are in the spotlight as viable alternatives to lithium-ion batteries in stationary storage and power grid applications. Among possible anode materials, Sb is one of the interesting candidates due to a combination of battery-type potential plateaus in the charge-discharge profiles, high capacity (theoretical capacity of 660 mAh g(-1)), and demonstrated good cyclic stability. The influence of Sb particle size (particularly at the nanoscale range) and the composition of Sb-carbon composites on the electrode performance, stability, and charge storage mechanism is systematically evaluated here for the first time. A range of Sb-carbon nanocomposites with varied Sb particle size (between 50 and ∼1 nm) are studied. The control of the particle size is achieved via varying the carbon and Sb weight ratio in the precursors. The shape of charge-discharge profiles, hysteresis, and the difference in cyclic stabilities and rate performance are analyzed. The nanocomposite with the smallest particle size (∼1 nm) and the largest carbon content provides the most stable cyclic behavior and a better rate capability but suffers from an increased hysteresis between charge and discharge curves. In situ synchrotron X-ray diffraction experiments indicate that the storage mechanism in the Sb-carbon nanocomposites containing Sb nanoparticles is different from the electrodes with bulkier, micron-sized Sb particles, and the electrochemical reaction proceeds through a number of crystalline intermediates.</div></front></TEI><affiliations><list><country><li>Australie</li></country></list><tree><country name="Australie"><noRegion><name sortKey="Ramireddy, Thrinathreddy" sort="Ramireddy, Thrinathreddy" uniqKey="Ramireddy T" first="Thrinathreddy" last="Ramireddy">Thrinathreddy Ramireddy</name></noRegion><name sortKey="Chen, Ying" sort="Chen, Ying" uniqKey="Chen Y" first="Ying" last="Chen">Ying Chen</name><name sortKey="Glushenkov, Alexey M" sort="Glushenkov, Alexey M" uniqKey="Glushenkov A" first="Alexey M" last="Glushenkov">Alexey M. Glushenkov</name><name sortKey="Leforestier, Jeremie" sort="Leforestier, Jeremie" uniqKey="Leforestier J" first="Jeremie" last="Leforestier">Jeremie Leforestier</name><name sortKey="Sharma, Neeraj" sort="Sharma, Neeraj" uniqKey="Sharma N" first="Neeraj" last="Sharma">Neeraj Sharma</name><name sortKey="Xing, Tan" sort="Xing, Tan" uniqKey="Xing T" first="Tan" last="Xing">Tan Xing</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 001736 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 001736 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= Wicri/Asie
|area= AustralieFrV1
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:27753471
|texte= Size and Composition Effects in Sb-Carbon Nanocomposites for Sodium-Ion Batteries.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:27753471" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a AustralieFrV1
| This area was generated with Dilib version V0.6.33. |  |